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Review Article

High-Performance Mg3Sb2-xBix Thermoelectrics: Progress and Perspective

Figure 3

(a) Band structure of Mg3Sb2 and Mg3Bi2. (b) A series of constant energy maps of Mg3Sb2 by ARPES. (c) Brillouin zone (BZ) and high-symmetry points in BZ of the trigonal structure of Mg3X2. (d) The diagram of Fermi surfaces of Mg3Bi2. (e) ARPES spectra along the high-symmetry directions of Mg3Sb2, the red line is the corresponding calculated band structures. (f) The band-resolved projected Crystal Orbital Hamiltonian Population (COHP) for the interaction between Mg1 and Mg2 in Mg3Sb2. Panels (a, b, d, e) are reproduced with permission from Ref. [48]. Published by The Royal Society of Chemistry. Panel (f) is reproduced with permission from Ref. [116]. Copyright 2019 Wiley Periodicals, Inc.

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