Boosting Circularly Polarized Luminescence of Organic Conjugated Systems <i>via</i> Twisted Intramolecular Charge Transfer

<div class="floats-full-page floats-full-page-figure"><h2>Figure 9</h2><div class="floats-full-page-caption"><div>Optimized geometries for <svg height="11.927pt" id="M109" style="vertical-align:-3.291101pt" version="1.1" viewbox="-0.0498162 -8.6359 11.1398 11.927" width="11.1398pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M449 634C442 637 425 643 405 650C376 660 341 666 307 666C181 666 98 590 98 485C98 400 170 343 215 310L246 288C307 243 343 204 343 147C343 67 291 18 219 18C104 18 61 124 51 202L23 199C28 124 27 71 27 47C47 22 122 -16 204 -16C324 -16 428 60 428 174C428 256 379 309 307 360L276 382C223 419 179 455 179 516C179 576 221 632 293 632C379 632 410 564 418 487L448 490C446 536 446 592 449 634Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,6.071,3.132)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z"></path></g></svg> and <svg height="11.8174pt" id="M110" style="vertical-align:-3.1815pt" version="1.1" viewbox="-0.0498162 -8.6359 11.1398 11.8174" width="11.1398pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M449 634C442 637 425 643 405 650C376 660 341 666 307 666C181 666 98 590 98 485C98 400 170 343 215 310L246 288C307 243 343 204 343 147C343 67 291 18 219 18C104 18 61 124 51 202L23 199C28 124 27 71 27 47C47 22 122 -16 204 -16C324 -16 428 60 428 174C428 256 379 309 307 360L276 382C223 419 179 455 179 516C179 576 221 632 293 632C379 632 410 564 418 487L448 490C446 536 446 592 449 634Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,6.071,3.132)"><path d="M389 0V32C297 38 291 46 291 118V635C234 613 175 595 109 583V556L161 554C203 552 207 547 207 497V118C207 46 201 38 110 32V0H389Z"></path></g></svg> of <i>o</i>-1 and <i>o</i>-2 using the state-specific PCM at the TD-DFT CAM-B3LYP/6-31+G(d,p) level in the crystalline states.</div></div><div class="floats-full-page-content"><table class="figure-group"><tr class="fig-image"><td><object data="https://d31iiq90dwlpfy.cloudfront.net/articles/research/volume-2020/3839160/figures/3839160.fig.009.svgz" name="3839160.fig.009" type="image/svg+xml"></object></td></tr></table></div></div>

Figure 9 | Boosting Circularly Polarized Luminescence of Organic Conjugated Systems <i>via</i> Twisted Intramolecular Charge Transfer

title

Figure 9: Boosting Circularly Polarized Luminescence of Organic Conjugated Systems <i>via</i> Twisted Intramolecular Charge Transfer

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Figure 9 | Boosting Circularly Polarized Luminescence of Organic Conjugated Systems via Twisted Intramolecular Charge Transfer

Figure 9

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<p>The open access journal <em>Research</em>, published in association with CAST, publishes innovative, wide-ranging research in life sciences, physical sciences, engineering and applied science.</p>


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The open access journal Research, published in association with CAST, publishes innovative, wide-ranging research in life sciences, physical sciences, engineering and applied science.