Research / 2020 / Article / Fig 3

Research Article

Additive-Mediated Selective Oxidation of Alcohols to Esters via Synergistic Effect Using Single Cation Cobalt Catalyst Stabilized with Inorganic Ligand

Figure 3

Oxidative esterification of benzylic alcohols or ethyl alcohol with different aromatic and long-chain aliphatic alcohols. Reaction conditions: cat. 1 (1.0 mol%), alcohols (R2) (1.0 mmol), 30% H2O2 (4.0 equiv), alcohols (R3) (2 mL), KCl (0.2 equiv) at 70°C for 36 h. Yields were determined using GC-Ms and column chromatography. Nitric acid (0.7 mmol). †Alcohols (R3) (2.0 equiv) and nitric acid (0.7 mmol).

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