Research / 2020 / Article / Fig 2

Research Article

Selective Dealkenylative Functionalization of Styrenes via C-C Bond Cleavage

Figure 2

Substrate scope for the aniline synthesis from styrenes. aStandard conditions: reactions were performed with styrene (0.3 mmol), TMSN3 (0.75 mmol), and MeSO3H (6.0 mmol) in CCl4 (1.0 mL) at 80°C for 4 h under atmosphere and isolated yields. bThe crude product was acetylated by acetyl chloride. cThe reaction was conducted at 40°C instead. dMeSO3H (1.5 mmol) was used as the acid. eTMSN3 (1.5 mmol) was used instead. CCl4: tetrachloromethane.