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Research Article

One-Step High-Temperature-Synthesized Single-Atom Platinum Catalyst for Efficient Selective Hydrogenation

Table 2

Pt1/MoC-catalyzed selective hydrogenation of quinoline compoundsa.

EntrySubstrateTarget productConv. (%)Sel. (%)TOF (h-1)bTOF (h-1)c

1d53.1>9921022522
268.3>9913521690
345.8>999061178
486.5>9917122054
563.996.712351359
681.3>9916091908
733.845.6308335

aReaction conditions: 0.005 mol% Pt, 5 mL toluene, 3 mmol substrate, 2 MPa H2, 150°C, 10 h. bAverage TOF. cTOF based on 20% substrate conversion. d5 h.