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Research Article

Ionic Liquid-Modified Porous Organometallic Polymers as Efficient and Selective Photocatalysts for Visible-Light-Driven CO2 Reduction

Table 1

Porosity properties, CO2 uptake capacities, and lifetimes of excited states.

Polymers (m2·g-1)a (cm3·g-1)bCO2 uptake (cm3·g-1)c (kJ·Mol-1)d (ns)e
273 K298 K

Re-POMP4520.3342.130.129.380
Re-POMP-IL1.03260.2440.629.440.393

aSpecific surface area calculated by using the BET method. bSingle point adsorption total pore volume at . cCO2 uptake capacities at 1 bar. dIsosteric heat of adsorption for CO2. eThe average photoluminescence lifetime of the polymer.