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Review Article

Current Research Trends and Perspectives on Solid-State Nanomaterials in Hydrogen Storage

Table 5

Experimentally measured hydrogen storage properties of selected MOFs, COFs, and PAFs.

FrameworkStorage conditions
Temp. (K)/Press. (bar)
BET surface area (m2 g–1)Hydrogen capability (wt%)Ref

MOF-5(a) 78/20
(b) 298/20
2500−3000(a) 4.5
(b) 1.0
[112]
IRMOF-8298/1018012.0[112]
MOF-177(a) 78/70
(b) 298/100
4600(a) 7.5
(b) 0.62
[113, 114]
NU-10077/56614310.0[52]
NU-10977/4570108.30[115, 116]
NU-110(a) 77/45
(b) 298/180
7140(a) 8.82
(b) 0.57
[115, 116]
MOF-399(a) 77/56
(b) 298/140
7157(a) 9.02
(b) 0.46
[116]
Cr-MIL-5377/1610203.1[117]
Al-MIL-5377/1610263.8[117]
Cu-MOF-5(a) 77/65
(b) 298/65
1154(a) 3.6
(b) 0.35
[118]
MOF-210(a) 77/80
(b) 298/80
6240(a) 17.6
(b) 2.7
[118]
Be-MOF(a) 77/ 1.0
(b) 298/95
4030(a) 1.6
(b) 2.3
[122]
COF-1(a) 77/1.0
(b) 77/70
711(a) 1.7
(b) 3.8
[135]
COF-5(a) 77/1.0
(b) 77/80
1590(a) 0.1
(b) 3.4
[135]
COF-102(a) 77/1.0
(b) 77/100
3620(a) 0.5
(b) 10.0
[135, 136]
COF-102-3(a) 77/100
(b) 300/100
(a) 6.5
(b) 26.7
[139]
COF-105(a) 77/1.0
(b) 77/80
3472(a) 0.6
(b) 10.0
[134, 135]
COF-108(a) 77/1.0
(b) 77/100
4210(a) 0.9
(b)10.0
[131133]
CTC-COF77/1.117101.12[140]
COF-105 (Li-doped)298/1006.84[145]
COF-108 (Li-doped)298/1006.73[145]
COF-340-CoCl2298/25074007.00[146]
PAF-177/4856007.0[27]
PAF-377/6029325.5[149, 150]
PAF-477/6022464.2[149, 150]
PAF-1 (KOH-treated)77/1.013203.06[151]
PAF-1 (Li-doped)77/1.210[153]
PAF-4 (Li-doped)77/100552520.7[152]
PAF-4 (Li-doped)233/10055254.9[152]
PAF-Mg233/1004479 (Langmuir)6.8[154]
PAF-Ca233/1004479 (Langmuir)6.4[154]
PAF-324298/1005372 (specific)6.32[155]
PAF-334298/10016.03[155]