Current Research Trends and Perspectives on Solid-State Nanomaterials in Hydrogen Storage

Table 5

Experimentally measured hydrogen storage properties of selected MOFs, COFs, and PAFs.


Framework	Storage conditions Temp. (K)/Press. (bar)	BET surface area (m² g^–1)	Hydrogen capability (wt%)	Ref

MOF-5	(a) 78/20 (b) 298/20	2500−3000	(a) 4.5 (b) 1.0	[112]
IRMOF-8	298/10	1801	2.0	[112]
MOF-177	(a) 78/70 (b) 298/100	4600	(a) 7.5 (b) 0.62	[113, 114]
NU-100	77/56	6143	10.0	[52]
NU-109	77/45	7010	8.30	[115, 116]
NU-110	(a) 77/45 (b) 298/180	7140	(a) 8.82 (b) 0.57	[115, 116]
MOF-399	(a) 77/56 (b) 298/140	7157	(a) 9.02 (b) 0.46	[116]
Cr-MIL-53	77/16	1020	3.1	[117]
Al-MIL-53	77/16	1026	3.8	[117]
Cu-MOF-5	(a) 77/65 (b) 298/65	1154	(a) 3.6 (b) 0.35	[118]
MOF-210	(a) 77/80 (b) 298/80	6240	(a) 17.6 (b) 2.7	[118]
Be-MOF	(a) 77/ 1.0 (b) 298/95	4030	(a) 1.6 (b) 2.3	[122]
COF-1	(a) 77/1.0 (b) 77/70	711	(a) 1.7 (b) 3.8	[135]
COF-5	(a) 77/1.0 (b) 77/80	1590	(a) 0.1 (b) 3.4	[135]
COF-102	(a) 77/1.0 (b) 77/100	3620	(a) 0.5 (b) 10.0	[135, 136]
COF-102-3	(a) 77/100 (b) 300/100	–	(a) 6.5 (b) 26.7	[139]
COF-105	(a) 77/1.0 (b) 77/80	3472	(a) 0.6 (b) 10.0	[134, 135]
COF-108	(a) 77/1.0 (b) 77/100	4210	(a) 0.9 (b)10.0	[131–133]
CTC-COF	77/1.1	1710	1.12	[140]
COF-105 (Li-doped)	298/100	–	6.84	[145]
COF-108 (Li-doped)	298/100	–	6.73	[145]
COF-340-CoCl₂	298/250	7400	7.00	[146]
PAF-1	77/48	5600	7.0	[27]
PAF-3	77/60	2932	5.5	[149, 150]
PAF-4	77/60	2246	4.2	[149, 150]
PAF-1 (KOH-treated)	77/1.0	1320	3.06	[151]
PAF-1 (Li-doped)	77/1.2	–	10	[153]
PAF-4 (Li-doped)	77/100	5525	20.7	[152]
PAF-4 (Li-doped)	233/100	5525	4.9	[152]
PAF-Mg	233/100	4479 (Langmuir)	6.8	[154]
PAF-Ca	233/100	4479 (Langmuir)	6.4	[154]
PAF-324	298/100	5372 (specific)	6.32	[155]
PAF-334	298/100	–	16.03	[155]