Research / 2021 / Article / Fig 4

Research Article

Intensifying Electron Utilization by Surface-Anchored Rh Complex for Enhanced Nicotinamide Cofactor Regeneration and Photoenzymatic CO2 Reduction

Figure 4

(a) Scheme of nicotinamide cofactor regeneration system. (b) The efficiency of NADH catalyzed by PCN@TA/PEI-Rha/b with different [TA]/[PEI], PCN, and PCN@TA/PEI with free Rh system. (c) The turnover frequency (TOF) of PCN@TA/PEI-Rh1/1, PCN@TA/PEI-Rh1/10, PCN@TA/PEI-Rh1/20, PCN, and PCN@TA/PEI with free Rh system. (d) Photoenzymatic conversion of CO2 enabled by PCN@TA/PEI-Rh. Reaction conditions: (b) , PBS buffer (pH 7.0, 100 mM), , , , visible light illumination (), , and room temperature; (d) , , , and .

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